Semiconductor Device and Method

ABSTRACT

In an embodiment, a method includes forming a first gate electrode over a substrate. The method also includes forming a first gate dielectric layer over the first gate electrode. The method also includes depositing a semiconductor layer over the first gate dielectric layer. The method also includes forming source/drain regions over the first gate dielectric layer and the semiconductor layer, the source/drain regions overlapping ends of the semiconductor layer. The method also includes forming a second gate dielectric layer over the semiconductor layer and the source/drain regions. The method also includes and forming a second gate electrode over the second gate dielectric layer.

PRIORITY CLAIM AND CROSS-REFERENCE

This application claims the benefit of the U.S. Provisional ApplicationNo. 63/134,256, filed on Jan. 6, 2021, and entitled “Switchable NAND andNOR Logic Gate Transistor,” it also claims benefit of the U.S.Provisional Application No. 63/118,141, filed on Nov. 25, 2020, entitled“Switchable NAND and NOR Logic Computing in Single Triple-Gate MonolayerTwo-Dimensional Material Channel Transistors”, both of whichapplications are hereby incorporated herein by reference.

BACKGROUND

Semiconductor devices are used in a variety of electronic applicationssuch as personal computers, cell phones, digital cameras, and otherelectronic equipment. Semiconductor devices are typically fabricated bysequentially depositing insulating or dielectric layers, conductivelayers, and semiconductor layers of material over a semiconductorsubstrate, and patterning the various material layers using lithographyprocesses to form circuit components and elements thereon.

The semiconductor industry continues to improve the integration densityof various electronic components (e.g., transistors, diodes, resistors,capacitors, etc.) by continual reductions in minimum feature size, whichallow more components to be integrated into a given area. However, asthe minimum features sizes are reduced, additional problems arise thatshould be addressed.

BRIEF DESCRIPTION OF THE DRAWINGS

Aspects of the present disclosure are best understood from the followingdetailed description when read with the accompanying figures. It isnoted that, in accordance with the standard practice in the industry,various features are not drawn to scale. In fact, the dimensions of thevarious features may be arbitrarily increased or reduced for clarity ofdiscussion.

FIGS. 1A and 1B illustrate a cross-sectional view of an intermediatestage in the formation of a double-gate transistor device and aschematic representation of a circuit including a double-gate transistordevice in accordance with some embodiments.

FIGS. 2A and 2B illustrate a truth table and exemplary voltage waveformsfor the inputs and outputs of the NAND and NOR logic functions of thedouble-gate transistor device in FIGS. 1A and 1B in accordance with someembodiments.

FIGS. 3A and 3B illustrate a cross-sectional view of an intermediatestage in the formation of a triple-gate transistor device and aschematic representation of a circuit including a triple-gate transistordevice in accordance with some embodiments.

FIGS. 4A and 4B illustrate a truth table and exemplary voltage waveformsfor the inputs and outputs of the NAND and NOR logic functions of thetriple-gate transistor device in FIGS. 3A and 3B in accordance with someembodiments.

FIGS. 5A, 5B, 6A, 6B, 7A, 7B, 8A, 8B, 9A, 9B, 10A, 10B, 11A, 11B, 12A,12B, 13A, 13B, 14A, 14B, 15A, 15B, 16A, 16B, 17A, 17B, 18A, and 18Billustrate the plan views and cross-sectional views of intermediatestages in the formation of a double-gate transistor device using atwo-dimensional material in accordance with some embodiments.

FIGS. 19A, 19B, 20A, 20B, 21A, 21B, 22A, 22B, 23A, and 23B illustratethe plan views and cross-sectional views of intermediate stages in theformation of a triple-gate transistor device using a two-dimensionalmaterial in accordance with some embodiments.

DETAILED DESCRIPTION

The following disclosure provides many different embodiments, orexamples, for implementing different features of the invention. Specificexamples of components and arrangements are described below to simplifythe present disclosure. These are, of course, merely examples and arenot intended to be limiting. For example, the formation of a firstfeature over or on a second feature in the description that follows mayinclude embodiments in which the first and second features are formed indirect contact, and may also include the embodiments in which additionalfeatures may be formed between the first and second features, such thatthe first and second features may not be in direct contact. In addition,the present disclosure may repeat reference numerals and/or letters inthe various examples. This repetition is for the purpose of simplicityand clarity and does not in itself dictate a relationship between thevarious embodiments and/or configurations discussed.

Further, spatially relative terms, such as “underlying,” “below,”“lower,” “overlying,” “upper” and the like, may be used herein for easeof description to describe one element or feature's relationship toanother element(s) or feature(s) as illustrated in the figures. Thespatially relative terms are intended to encompass differentorientations of the device in use or operation in addition to theorientation depicted in the figures. The apparatus may be otherwiseoriented (rotated 90 degrees or at other orientations) and the spatiallyrelative descriptors used herein may likewise be interpretedaccordingly.

Before addressing the illustrated embodiments specifically, certainadvantageous features and aspects of the present disclosed embodimentswill be addressed generally. In general terms, the present disclosure isa device and method of forming the same to provide a device with atwo-dimensional (2-D) material ultra-thin body transistor and logic gatefunction in a single device. The device design enables switchable NANDand NOR logic computing in a single multiple-gate transistor. The 2-Dmaterial layer may be a transition metal dichalcogenide (TMD) materiallayer. The disclosed embodiments simplify the logic gate layout and areaefficiency but also combine the NAND and NOR logic function in singledevice.

For example, in some embodiments, a double-gate transistor device with a2-D material layer channel can function as a NAND or NOR logic devicewith a voltage rematching operation being performed when switchingbetween the NAND and NOR logic functions. In some embodiments, atriple-gate transistor device with a 2-D material layer channel canfunction as a NAND or NOR logic device with an input to the deviceselecting between the NAND and NOR logic functions.

Embodiments discussed herein are to provide examples to enable making orusing the subject matter of this disclosure, and a person havingordinary skill in the art will readily understand modifications that canbe made while remaining within contemplated scopes of differentembodiments. Throughout the various views and illustrative embodiments,like reference numbers are used to designate like elements. Althoughmethod embodiments may be discussed as being performed in a particularorder, other method embodiments may be performed in any logical order.

FIGS. 1A and 1B illustrate a cross-sectional view of an intermediatestage in the formation of a double-gate transistor device and aschematic representation of a circuit including a double-gate transistordevice. In FIG. 1A, a double-gate transistor device 130 is illustratedat an intermediate stage of formation. The double-gate transistor device130 includes a channel layer 110 with a top gate electrode 118 and abottom gate electrode 104 on opposite sides of the channel layer 110such that the channel layer 110 is between the gate electrodes 118 and104. The top gate electrode 118 is separated from the channel layer 110by a top gate dielectric layer 116, and the bottom gate electrode 104 isseparated from the channel layer 110 by a bottom gate dielectric layer108. Source/drain regions 112A and 112B are formed on opposing ends ofthe channel layer 110 with each of the source/drain regions 112A and112B overlapping the respective end of the channel layer 110. The gateelectrodes 118 and 104, the source/drain regions 112A and 112B, the gatedielectrics 116 and 108, and the channel layer 110 are all formed over asubstrate 100. In some embodiments, a dielectric layer 102 is formed onthe substrate 100 and separates the structures from the substrate 100.

The top gate electrode 118 and the bottom gate electrode 104 bothcontrol whether current flows between source/drain regions 112A and 112Bin the channel layer 110. For example, in some embodiments, for currentto flow through the channel layer 110 between the source/drain regions112A and 112B, both of the top and bottom gate electrodes 118 and 104must have a high (“1”) input voltage applied to them. Said another way,for the double-gate transistor device 130 to be considered in an “ONstate, both the top and bottom gate electrodes 118 and 104 must have ahigh (“1”) input voltage applied to them. Thus, in these embodiments, ifonly one of the gates has a high input voltage, then no current (or avery small amount such that the transistor will be considered in an“OFF” state) will flow through the channel layer 110 between thesource/drain regions 112A and 112B.

FIG. 1B illustrates a schematic representation of a circuit includingthe double-gate transistor device 130. As illustrated in FIG. 1B, thedevice 130 and a load R_(S) is coupled between a supply voltage V_(DD)and a low voltage, such as ground. In some embodiments, the source/drainregion 112A is connected to an output node V_(OUT), and the source/drainregion 112B is connected to the low voltage node, such as ground. Asdiscussed above, the top and bottom gate electrodes 118 and 104 controlthe current flow through the double-gate transistor device 130, andthus, both the top and bottom gate electrodes 118 and 104 control theoutput V_(OUT).

FIGS. 2A and 2B illustrate a truth table and exemplary voltage waveformsfor the inputs and outputs of the NAND and NOR logic functions of thedouble-gate transistor device in FIGS. 1A and 1B.

In FIG. 2A, the truth table illustrates that the inputs to the logicfunctions of the double-gate transistor device 130 are the top gate(V_(TG)) and the bottom gate (V_(BG)) and the output is the source/drainregion 112A (V_(OUT)) (see. e.g., FIG. 1B). FIG. 2B illustrates examplevoltage waveforms for the inputs and output of the double-gatetransistor device 130 in a NAND and NOR configuration.

In the illustrated example of the NAND configuration, VDD is 2V andeither 0V for a low (“0”) input or 1V for a high (“1”) input is appliedto the inputs V_(TG) and V_(BG). If both V_(TG) and V_(BG) have highinputs (e.g., 1V), then the output V_(OUT) is pulled below the outputthreshold V_(DD)/2 to signify a “0” output. In all other cases in theNAND configuration, the output V_(OUT) is above the output thresholdV_(DD)/2 to signify a “1” output.

In the illustrated example of the NOR configuration, VDD is 2V, either0.5V for a low (“0”) input or 2V for a high (“1”) input is applied tothe input V_(TG), and either −0.5V for a low (“0”) input or 2.5V for ahigh (“1”) input is applied to the input V_(BG).

Please note that the voltage inputs for the NOR configuration isdifferent than the NAND configuration such that the double-gatetransistor device 130 requires a voltage rematch step when switchingbetween the two different configurations. For the NOR configuration, ifboth V_(TG) and V_(BG) have low inputs (e.g., 0.5V and −0.5V,respectively), then the output V_(OUT) is above the output thresholdV_(DD)/2 to signify a “l” output. In all other cases in the NORconfiguration, the output V_(OUT) is below the output threshold V_(DD)/2to signify a “0” output.

Although specific voltages are illustrated in FIG. 2B, the disclosure isnot limited to these specific voltages for the NAND and NOR logicconfigurations. For example, other voltage levels of V_(DD) and theinputs V_(TG) and V_(BG) could be used.

FIGS. 3A and 3B illustrate a cross-sectional view of an intermediatestage in the formation of a triple-gate transistor device 140 and aschematic view including a triple-gate MOSFET device 140. Thetriple-gate transistor device 140 is similar to the double-gatetransistor device 130 in FIGS. 1A and 1B except that the triple-gatetransistor device 140 has two bottom gate electrodes 104A and 104B.Details regarding this embodiment that are similar to those for thepreviously described embodiment will not be repeated herein.

As illustrated in FIG. 3A, the bottom gate electrode 104A is near thesource/drain region 112A and the bottom gate electrode is near thesource/drain region 112B while the top gate electrode 118 spans theentirety of the area between the source/drain regions 112A and 112B, andthus, is near both source/drain regions 112A and 112B.

The top gate electrode 118 and the bottom gate electrodes 104A and 104Beach have a part in controlling whether current flows betweensource/drain regions 112A and 112B in the channel layer 110. Forexample, in some embodiments, for current to flow through the channellayer 110 between the source/drain regions 112A and 112B, at least twoof the three top and bottom gate electrodes 118, 104A, and 104B musthave a high (“1”) input voltage applied to them. Said another way, forthe triple-gate transistor device 140 to be considered in an “ON state,at least two of the three top and bottom gate electrodes 118, 104A, and104B must have a high (“1”) input voltage applied to them. Thus, inthese embodiments, if only one of the gates has a high input voltage,then no current (or a very small amount such that the transistor will beconsidered in an “OFF” state) will flow through the channel layer 110between the source/drain regions 112A and 112B.

FIG. 3B illustrates a schematic representation of a circuit includingthe triple-gate transistor device 140. As illustrated in FIG. 3B, thedevice 140 and a load R_(S) is coupled between a supply voltage V_(DD)and a low voltage, such as ground. In some embodiments, the source/drainregion 112A is connected to an output node V_(OUT), and the source/drainregion 112B is connected to the low voltage node, such as ground. Asdiscussed above, the top and bottom gate electrodes 118, 104A, and 104Bcontrol the current flow through the triple-gate transistor device 140,and thus, each of the top and bottom gate electrodes 118, 104A, and 104Bhave a part in controlling the output V_(OUT).

FIGS. 4A and 4B illustrate a truth table and exemplary voltage waveformsfor the inputs and outputs of the NAND and NOR logic functions of thetriple-gate transistor device 140 in FIGS. 3A and 3B.

In FIG. 4A, the truth table illustrates that the inputs to the logicfunctions of the triple-gate transistor device 140 are the top gate(V_(TG)), the bottom gate electrode 104A (V_(BD)), and the bottom gateelectrode 104B (V_(BS)), and the output is the source/drain region 112A(V_(OUT)) (see. e.g., FIG. 3B). FIG. 4B illustrates example voltagewaveforms for the inputs and output of the triple-gate transistor device140 in a NAND and NOR configuration.

In the illustrated example, VDD is 2V, either −0.5V for a low (“0”)input or 2V for a high (“1”) input is applied to the inputs V_(B)D andV_(BS), and either 0.75V for a low (“0”) input or 2V for a high (“1”)input is applied to the input V_(TG). In the illustrated example, theinput VTG selects if the triple-gate transistor device 140 is in a NANDor NOR configuration. For example, if V_(TG) has a low voltage input(e.g., 0.75V), then the device 140 is in a NAND configuration, and ifV_(TG) has a high voltage input (e.g., 2V), then the device 140 is in aNOR configuration. Unlike the double-gate transistor device 130, thetriple-gate transistor device 140 does not require a voltage rematchprocess when switching between NAND and NOR configurations.

In the NAND configuration, if V_(TG) has a low input (e.g., 0.75V) andif both V_(BS) and V_(B)D have high inputs (e.g., 2V), then the outputV_(OUT) is pulled below the output threshold V_(DD)/2 to signify a “0”output. In all other cases in the NAND configuration, the output V_(OUT)is above the output threshold V_(DD)/2 to signify a “l” output.

In the NOR configuration, if V_(TG) has a high input (e.g., 2V) and ifboth V_(BS) and V_(B)D have low inputs (e.g., −0.5V), then the outputV_(OUT) is above the output threshold V_(DD)/2 to signify a “10” output.In all other cases in the NOR configuration, the output V_(OUT) is belowthe output threshold V_(DD)/2 to signify a “0” output.

Although specific voltages are illustrated in FIG. 4B, the disclosure isnot limited to these specific voltages for the NAND and NOR logicconfigurations. For example, other voltage levels of V_(DD) and theinputs V_(TG), V_(BS), and V_(B)D could be used.

FIGS. 5A, 5B, 6A, 6B, 7A, 7B, 8A, 8B, 9A, 9B, 10A, 10B, 11A, 11B, 12A,12B, 13A, 13B, 14A, 14B, 15A, 15B, 16A, 16B, 17A, 17B, 18A, and 18Billustrate the plan views and cross-sectional views of intermediatestages in the formation of a double-gate transistor device using atwo-dimensional material in accordance with some embodiments. Thesefigure numbers are followed by a letter “A,” or “B” wherein the letter“B” indicates that the respective view is a plan view (a top view), theletter “A” indicates that the respective figure is obtained from thereference cross-section A-A in the respective plan view. For example,FIG. 5A illustrates the reference cross-section A-A in FIG. 5B.

Referring to FIGS. 5A and 5B a substrate 100 is provided. In accordancewith some embodiments of the present disclosure, the substrate 100 maybe a semiconductor substrate, such as a bulk semiconductor substrate, aSemiconductor-On-Insulator (SOI) substrate, or the like. The substrate100 may be doped (e.g., with a p-type or an n-type dopant) or undoped.The substrate 100 may be a part of wafer 10, such as a silicon wafer.Generally, an SOI substrate is a layer of a semiconductor materialformed on an insulator layer. The insulator layer may be, for example, aBuried Oxide (BOX) layer, a silicon oxide layer, or the like. Theinsulator layer is provided on a substrate, typically a silicon or glasssubstrate. Other substrates such as a multi-layered or gradientsubstrate may also be used. In some embodiments, the semiconductormaterial of substrate 100 may include silicon; germanium; a compoundsemiconductor including carbon-doped silicon, gallium arsenic, galliumphosphide, indium phosphide, indium arsenide, and/or indium antimonide;an alloy semiconductor including SiGe, carbon-doped silicon, GaAsP,AlInAs, AlGaAs, GaInAs, GaInP, and/or GaInAsP; or combinations thereof.

Isolation layer 102 is formed over substrate 100. In accordance withsome embodiments of the present disclosure, the isolation layer 102 isin physical contact with substrate 100. In accordance with alternativeembodiments of the present disclosure, between the isolation layer 102and substrate 100, there may be other layers and devices including, andnot limited to, dielectric layers, metal features, or the like. Forexample, there may be inter-layer dielectrics, inter-metal dielectrics(which may include low-k dielectric layers), and/or the like. There maybe, or may not be, integrated circuit devices such as passive devices(capacitors, resistors, inductors, or the like) and/or active devices(transistors, diodes, or the like) formed between the isolation layer102 and the substrate 100.

In accordance with some embodiments of the present disclosure, theisolation layer 102 is formed of or comprises a nitride such as siliconnitride, an oxide such as silicon oxide, silicon oxy-fluoride (SiOF),silicon oxy-carbide (SiOC), or the like, or a high-k dielectric materialsuch as aluminum oxide, hafnium oxide, zirconium oxide, lanthanum oxide,or the like. The isolation layer 102 may be a crystalline layer (singlecrystalline or polycrystalline) or an amorphous layer. The isolationlayer 102 may have a single-layer structure or a composite structureincluding a plurality of layers. For example, the isolation layer 102may include a bi-layer structure, a tri-layer structure, or the like.The bi-layer structure may include two layers formed of differentmaterials, for example, a silicon oxide layer and a silicon nitridelayer over the silicon oxide layer. In accordance with some embodimentsof the present disclosure, the thickness of the isolation layer 102 isin the range between about 5 nm and about 20 nm.

The formation process of the isolation layer 102 may include one or aplurality of deposition process(es) including, for example, a PlasmaEnhanced Chemical Vapor Deposition (PECVD) process, a Plasma EnhancedAtomic Layer Deposition (PEALD) process, an Atomic Layer Deposition(ALD) process, a Chemical Vapor Deposition (CVD) process, or the like.In accordance with some embodiments of the present disclosure, theisolation layer 102 may also be formed through thermal oxidation,chemical oxidation, or the like, for example, when the isolation layer102 comprises silicon oxide and when substrate 100 is formed of orcomprises silicon.

In FIGS. 6A and 6B, a conductive layer 104 is formed over the isolationlayer 102 and the substrate 100. The conductive layer 104 issubsequently patterned to form a bottom gate electrode 104 (see, e.g.,FIGS. 9A-B). The conductive layer 104 may include a metal-containingmaterial such as TiN, TiO, TaN, TaC, Co, Ru, Al, W, combinationsthereof, or multi-layers thereof. For example, although a singleconductive layer 104 is illustrated in FIG. 6A-B, the conductive layer104 may comprise any number of seed layers, liner layers, any number ofwork function tuning layers. The conductive layer 104 may be depositedby physical vapor deposition (PVD), CVD, sputter deposition, plating, orother techniques known and used in the art for depositing conductivematerials. After the forming of the conductive layer 104, aplanarization process, such as a CMP, may be performed to planarize atop surface of the conductive layer 104.

In FIGS. 7A and 7B, a mask layer 106 is formed over the conductive layer104. The mask layer 106 is subsequently patterned and will be used topattern the conductive layer 104. The mask layer 106 may include, forexample, SiO_(X), SiN, SiON, the like, or a combination thereof. Themask layer 106 may be deposited by any suitable method, such as CVD,plasma-enhanced CVD (PECVD), or the like. In some embodiments, the masklayer 106 is a photo resist.

In FIGS. 8A and 8B, the mask layer 106 is patterned over the conductivelayer 104 corresponding to the location of the bottom gate electrode104. The mask layer 106 is patterned using acceptable photolithographyand etching techniques to form a patterned mask 106. The pattern of themask 106 then may be transferred to the conductive layer 104 (see FIGS.9A-B).

In FIGS. 9A and 9B, the patterned mask 106 is then used to pattern theconductive layer 104 to form a bottom gate electrode 104. After the maskis patterned, the exposed portions of the conductive layer 104 (e.g.,portions of the conductive layer 104 not under the mask) are removed,such as by using an acceptable etching process, such as by wet or dryetching. The remaining portions of the conductive layer 104 form thebottom gate electrode 104. In this embodiment, the bottom gate electrodemay have sidewalls that are sloped (e.g., sidewalls that widen) from atop surface of the bottom gate electrode 104 to the bottom surface ofthe bottom gate electrode 104. The sloped sidewalls of the bottom gateelectrode 104 mean that in some embodiments, the bottom gate electrode104 has a larger bottom surface than a top surface. In some embodiments,the sidewalls of the bottom gate electrode 104 are not sloped and areperpendicular to a major surface of the substrate 100.

In FIGS. 10A and 10B, the patterned mask 106 is removed to expose a topsurface of the bottom gate electrode 104. In some embodiments, thepatterned mask 106 is removed with an etch process, a planarizationprocess, such as a CMP, the like or a combination thereof. In someembodiments, the patterned mask 106 is removed during the patterning ofthe conductive layer 104, and a separate etch process to remove thepatterned mask 106 is not needed.

In FIGS. 11A and 111B, a bottom gate dielectric layer 108 is formed. Thebottom gate dielectric layer 108 and bottom gate electrode 104 may bereferred to as a bottom gate stack. The bottom gate dielectric layer 108is formed to cover a top surface and sidewalls of the bottom gateelectrode 104. In accordance with some embodiments, the bottom gatedielectric layer 108 comprise silicon oxide, silicon nitride, ormultilayers thereof. In some embodiments, the bottom gate dielectriclayer 108 include a high-k dielectric material, and in theseembodiments, the bottom gate dielectric layer 108 may have a k valuegreater than about 7.0, and may include a metal oxide or a silicate ofHf, Al, Zr, La, Mg, Ba, Ti, Pb, and combinations thereof. The formationmethods of the bottom gate dielectric layer 108 may includeMolecular-Beam Deposition (MBD), ALD, PECVD, and the like. For example,the bottom gate dielectric layer 108 may include a silicon oxide layerand a high-k dielectric layer over the silicon oxide layer.

In FIGS. 12A and 12B, a semiconductor layer 110 is formed throughdeposition. The semiconductor layer 110 will be used as a channel layeror active layer in the subsequently formed transistor. In someembodiments, the semiconductor layer 110 covers a top surface andsidewalls of the bottom gate dielectric layer 108. In accordance withsome embodiments of the present disclosure, the semiconductor layer 110is formed of a 2D material, which is also referred to as a Van Der Waalsmaterial. The 2D material includes one or a plurality of monolayers.Strong bonds such as covalence bonds are formed within the monolayers tobond the atoms in the same monolayer to each other. The bonding forcebetween neighboring monolayers is Van Der Waals force, which is a weakforce.

In some embodiments, the semiconductor layer 110 may be formed of orcomprise MoS₂, MoSe₂, WS₂, WSe₂, InSe, or the like. In some embodiments,the semiconductor layer 110 is a semiconductor oxide and may includezinc oxide, indium gallium zinc oxide (IGZO), or the like.

In accordance with some embodiments of the present disclosure,semiconductor layer 28 is formed of or comprises a Transition MetalDichalcogenide (TMD) material, which comprises the compound of atransition metal and a group-VIA element. The transition metal mayinclude W, Mo, Ti, V, Co, Ni, Zr, Tc, Rh, Pd, Hf, Ta, Re, Ir, Pt, or thelike. The group-VIA element may be sulfur (S), selenium (Se), tellurium(Te), or the like.

As illustrated in FIGS. 12A and 12B, in some embodiments of the presentdisclosure, the semiconductor layer 110 is a conformal layer, with athickness of vertical portions and a thickness of the horizontalportions close to each other, for example, with a difference smallerthan about 20 percent (or 10 percent or smaller) of either ofthicknesses. In accordance with some embodiments of the presentdisclosure, the semiconductor layer 110 is deposited using CVD, withMoO₃ powder and sulfur (s) (or Se) powder as precursors, and nitrogen(N₂) as a carrier gas. The flow rate of each of the MoO₃ powder and Sepowder may be in the range between about 5 sccm and about 100 sccm. Inaccordance with alternative embodiments of the present disclosure, PECVDor another applicable method is used. The deposition temperature may bebetween about 750° C. and about 1,000° C. in accordance with someembodiments of the present disclosure, and higher or lower temperaturesmay be used. The deposition duration may be in the range between about10 minutes and about 1 hour. The process conditions are controlled toachieve the desirable total count of monolayers. In accordance with someembodiments of the present disclosure, semiconductor layer 28 includesbetween 1 (a single monolayer) and about 4 monolayers, while moremonolayers maybe formed. Correspondingly, the thickness of thesemiconductor layer 110 may be in the range between about 0.7 nm(corresponding to a single monolayer) and about 3 nm (corresponding tofour monolayers).

However, the processes as described above are intended to beillustrative only and are not intended to be limiting upon theembodiments. Rather, any suitable process of forming or placing thesemiconductor layer 110 onto the bottom gate dielectric layer 108 may beutilized. For example, a CVD process using precursors such as MoO₃ andH₂S, or precursors such as Mo and H₂S, may also be utilized. In someembodiments, a physical vapor deposition PVD process which utilizes aMoS₂ target may be utilized. Additionally, any other suitable processes,such as dissociation of spin-on coated (NH₄)₂MoS₄, or growing thesemiconductor layer 110 on a substrate such as copper, nickel, orsapphire and then transferring the semiconductor layer 110 to the bottomgate dielectric layer 108, may be used.

In some embodiments, the TMD material for the semiconductor layer 110may be formed in bulk separately from the substrate 100 and then a layerof the bulk semiconductor layer material is removed and placed onto thebottom gate dielectric layer 108. For example, a mechanical exfoliationusing, e.g., a Scotch-type tape may be utilized to remove a layer orlayers of TMD materials from a bulk TMD material and then the TMDmaterial may be transferred to the bottom gate dielectric layer 108 toform the semiconductor layer 110. In some embodiments, a liquidexfoliation of the TMD materials from the bulk TMD material using, e.g.,an intercalation such as n-butyl lithium dissolved in hexane may beutilized to remove the semiconductor layer 110 for transport to thebottom gate dielectric layer 108. Any suitable method of forming orplacing the semiconductor layer 110 may be used, and all such methodsare fully intended to be included within the scope of the embodiments.

In FIGS. 13A and 13B, the semiconductor layer 110 is patterned. Thesemiconductor layer 110 is patterned to define the active area of thesubsequently formed transistor (see, e.g., FIGS. 18A-B). In someembodiments, after the patterning process, the bottom gate electrode 104is wider than the semiconductor layer 110 in the direction of currentflow between the subsequently formed source/drain regions 112 (see FIGS.14A and 14B). The patterning may be achieved using a photoresist orother masks (not shown) and one or more etching processes. For example,a photoresist may be formed over the semiconductor layer 110. Thephotoresist is patterned to expose the portion of the semiconductorlayer 110 to be removed. The photoresist can be formed by using aspin-on technique and can be patterned using acceptable photolithographytechniques. Once the photoresist is patterned, an etching process isperformed on the semiconductor layer 110, and the photoresist may act asa mask to prevent the desired semiconductor layer 110 from beingremoved. After the one or more etching processes, the photoresist isremoved, such as by an acceptable ashing process.

In FIGS. 14A and 14B, the source/drain regions 112 (112A and 112B) areformed over the semiconductor layer 110 and the bottom gate dielectriclayer 108. In the illustrated embodiment, the source/drain regions 112are formed on the bottom gate dielectric layer 108 and the semiconductorlayer 110. The source/drain regions 112 overlap ends of the patternedsemiconductor layer 110 which acts as a channel layer for thesubsequently formed transistor and a portion of the semiconductor layer110 is exposed between the overlapped ends of the source/drain regions112. The source/drain regions 112 may be formed by PVD, CVD, sputterdeposition, plating, such as electroplating or electroless plating, orother techniques known and used in the art for depositing conductivematerial. The conductive material may include a metal-containingmaterial such as TiN, TiO, TaN, TaC, Co, Ru, Al, W, Ni, Ti, Ni, Bi, Sb,Sn combinations thereof, or multi-layers thereof. For example, althougha single conductive layer 104 is illustrated in FIG. 14A-B, thesource/drain regions 112 may comprise more than one layer of conductivematerial.

As an example to form the source/drain regions 112 with a platingprocess, a photo resist is then formed and patterned over thesemiconductor layer 110 and the bottom gate dielectric layer 108. Thephoto resist may be formed by spin coating or the like and may beexposed to light for patterning. The pattern of the photo resistcorresponds to the source/drain regions 112. The patterning formsopenings through the photo resist to expose the areas of thesemiconductor layer 110 where the source/drain regions 112 are tooverlap and contact the semiconductor layer 110. A seed layer (notshown) is formed over the photoresist and in the openings. In someembodiments, the seed layer is a metal layer, which may be a singlelayer or a composite layer comprising a plurality of sub-layers formedof different materials. In some embodiments, the seed layer comprises atitanium layer and a copper layer over the titanium layer. The seedlayer may be formed using, for example, PVD or the like. A conductivematerial is formed on the seed layer in the openings of the photoresist. The conductive material may be formed by plating, such aselectroplating or electroless plating, or the like. Then, the photoresist and portions of the seed layer on which the conductive materialis not formed are removed. The photo resist may be removed by anacceptable ashing or stripping process, such as using an oxygen plasmaor the like. Once the photo resist is removed, exposed portions of theseed layer are removed, such as by using an acceptable etching process,such as by wet or dry etching. The remaining portions of the seed layerand conductive material form the thermal pads 182. In the embodiment,where the thermal pads 182 are formed differently, more photo resist andpatterning steps may be utilized.

In FIGS. 15A and 15B, a top gate dielectric layer 116 is formed over thesource/drain regions 112 and the semiconductor layer 110. The top gatedielectric layer 116 is physically contacting the semiconductor layer110 between the source/drain regions 112. In accordance with someembodiments, the top gate dielectric layer 116 comprise silicon oxide,silicon nitride, or multilayers thereof. In some embodiments, the topgate dielectric layer 116 include a high-k dielectric material, and inthese embodiments, the top gate dielectric layer 116 may have a k valuegreater than about 7.0, and may include a metal oxide or a silicate ofHf, Al, Zr, La, Mg, Ba, Ti, Pb, and combinations thereof. The formationmethods of the top gate dielectric layer 116 may include MBD, ALD,PECVD, and the like. For example, the top gate dielectric layer 116 mayinclude a silicon oxide layer and a high-k dielectric layer over thesilicon oxide layer.

The top gate dielectric layer 116 can have a same or different materialcomposition as the bottom gate dielectric layer 108. The top gatedielectric layer 116 can have a same or different thickness as thebottom gate dielectric layer 108. For example, in some embodiments, thetop gate dielectric layer 116 has a same material composition and a samethickness as the bottom gate dielectric layer 108.

In FIGS. 16A and 16B, a top gate electrode 118 is formed over theisolation top gate dielectric layer 116 between the source/drain regions112. The top gate dielectric layer 116 and top gate electrode 118 may bereferred to as a top gate stack. The top gate electrode 118 may beformed of similar materials and with similar processes as the bottomgate electrode 104 and/or the source/drain regions 112. Although asingle layer is illustrated for the top gate electrode 118 in FIG.16A-B, the top gate electrode 118 may comprise any number of seedlayers, liner layers, any number of work function tuning layers. The topgate electrode 118 can have a same or different material composition asthe bottom gate electrode 104. The top gate electrode 118 can have asame or different thickness as the bottom gate electrode 104. Forexample, in some embodiments, the top gate electrode 118 has a samematerial composition and a same thickness as the bottom gate electrode104.

In FIGS. 17A and 17B, the top gate dielectric layer 116 is patterned.The top gate dielectric layer 116 is patterned to form openings 120 toexpose portions of the source/drain regions 112 and opening 122 toexpose a portion of the bottom gate electrode 104. The openings 120 and122 may be formed by acceptable photolithography and etching techniques.For example, a photo resist or hard mask may be used as a mask for anetching process. After the mask is patterned, the exposed portions ofthe top gate dielectric layer 116 (e.g., portions of the top gatedielectric layer 116 not under the mask) are removed, such as by usingan acceptable etching process, such as by wet or dry etching to exposeportions of the source/drain regions 112 and the bottom gate electrode104.

In FIGS. 18A and 18B, source/drain contacts 124 and bottom gate contact126 is formed in the openings 120 and 122, respectively. After theopenings are formed, a liner, such as a diffusion barrier layer, anadhesion layer, or the like, and a conductive material are formed in theopenings. The liner may include titanium, titanium nitride, tantalum,tantalum nitride, or the like. The conductive material may be copper, acopper alloy, silver, gold, tungsten, cobalt, aluminum, nickel, or thelike. A planarization process, such as a CMP, may be performed to removeexcess material from a surface of the top gate dielectric 116. Theremaining liner and conductive material form the source/drain contacts124 and bottom gate contact 126 in the openings. The source/draincontacts 124 are physically and electrically coupled to the source/drainregions 112, and the bottom gate contact 126 is physically andelectrically coupled to the bottom gate electrode 104. The source/draincontacts 124 and the bottom gate contact 126 may be formed in differentprocesses, or may be formed in the same process.

Although a single double-gate transistor device 130 is illustrated asbeing formed on the substrate 100, many double-gate transistor devices130 may be formed on the same substrate 100 and electrically connectedto form circuits.

Although not illustrated, the double-gate transistor device 130 mayundergo subsequent processing. For example, an interconnect structureincluding one or more inter-layer dielectrics, inter-metal dielectrics,conductive vias and conductive lines may be formed over the double-gatetransistor device 130.

FIGS. 19A, 19B, 20A, 20B, 21A, 21B, 22A, 22B, 23A, and 23B illustratethe plan views and cross-sectional views of intermediate stages in theformation of a triple-gate transistor device 140 using a two-dimensionalmaterial in accordance with some embodiments. These figure numbers arefollowed by a letter “A,” or “B” wherein the letter “B” indicates thatthe respective view is a plan view (a top view), the letter “A”indicates that the respective figure is obtained from the referencecross-section A-A in the respective plan view. For example, FIG. 19Aillustrates the reference cross-section A-A in FIG. 19B.

This embodiment is similar to the double-gate transistor device 130 ofFIGS. 5A through 18B except that the triple-gate embodiment has twobottom gate electrodes 104A and 104B. Details regarding this embodimentthat are similar to those for the previously described embodiment willnot be repeated herein.

FIGS. 19A and 19B are at a similar stage of processing as FIGS. 7A and7B and the description of achieving this structure is not repeatedherein. FIGS. 19A and 19B illustrate the isolation layer 102 over thesubstrate 100, the conductive layer 104 over the isolation layer 102,and the mask layer 106 over the conductive layer 104.

In FIGS. 20A and 20B, the mask layer 106 is patterned over theconductive layer 104 corresponding to the location of the bottom gateelectrodes 104A and 104B. The mask layer 106 is patterned usingacceptable photolithography and etching techniques to form a patternedmask 106. The pattern of the mask 106 then may be transferred to theconductive layer 104 (see FIGS. 21A-B).

In FIGS. 21A and 21B, the patterned mask 106 is then used to pattern theconductive layer 104 to form a bottom gate electrodes 104A and 104B.After the mask is patterned, the exposed portions of the conductivelayer 104 (e.g., portions of the conductive layer 104 not under themask) are removed, such as by using an acceptable etching process, suchas by wet or dry etching. The remaining portions of the conductive layer104 form the bottom gate electrodes 104A and 104B. In this embodiment,the bottom gate electrodes 104A and 104B may have sidewalls that aresloped (e.g., sidewalls that widen) from a top surface of the bottomgate electrodes 104A and 104B to the bottom surface of the bottom gateelectrodes 104A and 104B. The sloped sidewalls of the bottom gateelectrodes 104A and 104B mean that in some embodiments, the bottom gateelectrodes 104A and 104B have larger bottom surfaces than top surfaces.In some embodiments, the sidewalls of the bottom gate electrodes 104Aand 104B are not sloped and are perpendicular to a major surface of thesubstrate 100.

In FIGS. 22A and 22B, the patterned mask 106 is removed to expose a topsurface of the bottom gate electrodes 104A and 104B. In someembodiments, the patterned mask 106 is removed with an etch process, aplanarization process, such as a CMP, the like or a combination thereof.In some embodiments, the patterned mask 106 is removed during thepatterning of the conductive layer 104, and a separate etch process toremove the patterned mask 106 is not needed.

FIGS. 23A and 23B illustrate further processing on the structures ofFIGS. 22A and 22B. The processing between these figures is similar tothe processing illustrated and described above in reference to FIGS.10A-B through 18A-B with FIGS. 18A-B being an equivalent intermediatestage as FIGS. 23A-B and the descriptions are not repeated herein.

In FIGS. 23A and 23B, the triple-gate transistor device 140 isillustrated. In the triple-gate transistor device 140 of FIGS. 23A-B,the semiconductor layer 110 extends over top surfaces and innersidewalls of the bottom gate electrodes 104A and 104B, where the innersidewalls of the bottom gate electrodes 104A and 104B face each other.In some embodiments, the semiconductor layer has a bottom surface thatis lower than top surfaces of both of the bottom gate electrodes 104Aand 104B. Further, in some embodiments, the top gate electrode 118 has abottom surface that is lower than a top surface of the semiconductorlayer 110.

In some embodiments, the devices 130 or 140 can be configured to utilizea ferroelectric structure. Specifically, in some embodiments, the bottomgate dielectric layer 108 can be replaced with a ferroelectric layersuch that the device can operate as a ferroelectric FET (FeFET) and/orferroelectric memory. In some embodiments, the ferroelectric structurethat replaces bottom gate dielectric layer 108 may be made of hafniumzirconium oxide or the like.

In some embodiments, the devices 130 or 140 can be configured to utilizea floating gate memory structure. Specifically, in some embodiments, thebottom gate dielectric layer 108 can be replaced with a floating gatememory structure such that the device can operate as a floating gatememory. In some embodiments, the floating gate memory structure thatreplaces bottom gate dielectric layer 108 may be made of a stack ofthree layers such as aluminum oxide/hafnium oxide/aluminum oxide,silicon oxide/silicon nitride/silicon oxide, or the like. In theembodiments with the ferroelectric structure or the floating gate memorystructure, the transistor device's transfer curve can be modulated tocreate a memory window.

Embodiments may achieve advantages. The present disclosure is a deviceand method of forming the same to provide a device with atwo-dimensional (2-D) material ultra-thin body transistor and logic gatefunction in a single device. The device design enables switchable NANDand NOR logic computing in a single multiple-gate transistor. The 2-Dmaterial layer may be a transition metal dichalcogenide (TMD) materiallayer. The disclosed embodiments simplify the logic gate layout and areaefficiency but also combine the NAND and NOR logic function in singledevice.

In some embodiments, a double-gate transistor device with a 2-D materiallayer channel can function as a NAND or NOR logic device with a voltagerematching operation being performed when switching between the NAND andNOR logic functions. In some embodiments, a triple-gate transistordevice with a 2-D material layer channel can function as a NAND or NORlogic device with an input to the device selecting between the NAND andNOR logic functions.

In an embodiment, a method includes forming a first gate electrode overa substrate. The method also includes forming a first gate dielectriclayer over the first gate electrode. The method also includes depositinga semiconductor layer over the first gate dielectric layer. The methodalso includes forming source/drain regions over the first gatedielectric layer and the semiconductor layer, the source/drain regionsoverlapping ends of the semiconductor layer. The method also includesforming a second gate dielectric layer over the semiconductor layer andthe source/drain regions. The method also includes and forming a secondgate electrode over the second gate dielectric layer.

Embodiments may include one or more of the following features. Themethod where the depositing the semiconductor layer includes depositinga transition metal dichalcogenide layer. The transition metaldichalcogenide layer includes include MoS2, MoSe2, WS2, WSe2, or InSe.The transition metal dichalcogenide layer is performed using chemicalvapor deposition with moo3 powder and sulfur powder as precursors. Thedepositing the semiconductor layer includes depositing a semiconductoroxide layer. The semiconductor oxide layer includes zinc oxide or indiumgallium zinc oxide. The first gate dielectric layer and the second gatedielectric layer each include a high-k dielectric material. The methodfurther including forming an isolation layer over the substrate, thefirst gate electrode being over the isolation layer. The method furtherincluding forming a third gate electrode over the substrate, the firstgate dielectric layer and the semiconductor layer being over the thirdgate electrode, the third gate electrode being spaced apart from thefirst gate electrode. The semiconductor layer is a conformal layer.

In an embodiment, a device includes a first gate electrode over asubstrate. The device also includes a first high-k gate dielectric layerover the first gate electrode. The device also includes a transitionmetal dichalcogenide layer over the first high-k gate dielectric layer.The device also includes source/drain regions over the first high-k gatedielectric layer and the transition metal dichalcogenide layer, thesource/drain regions overlapping ends of the transition metaldichalcogenide layer. The device also includes a second high-k gatedielectric layer over the transition metal dichalcogenide layer and thesource/drain regions. The device also includes and a second gateelectrode over the second high-k gate dielectric layer.

Embodiments may include one or more of the following features. Thedevice where the transition metal dichalcogenide layer includes aplurality of monolayers. The transition metal dichalcogenide layerincludes include MoS2, MoSe2, WS2, WSe2, or InSe. The device furtherincluding a third gate electrode over the substrate, the first high-kgate dielectric layer and the transition metal dichalcogenide layerbeing over the third gate electrode, the third gate electrode beingspaced apart from the first gate electrode. The transition metaldichalcogenide layer has a bottom surface lower than top surfaces of thefirst gate electrode and the third gate electrode. The device isconfigured to operate as a NAND gate with the first gate electrode andthe second gate electrode being inputs to the NAND gate and one of thesource/drain regions being an output of the NAND gate. The device isconfigured to operate as a NOR gate with the first gate electrode andthe second gate electrode being inputs to the NOR gate and one of thesource/drain regions being an output of the NOR gate.

In an embodiment, a device includes a dielectric layer. The device alsoincludes a first gate electrode over the dielectric layer. The devicealso includes a first gate dielectric layer over and contacting a topsurface and sidewalls of the first gate electrode. The device alsoincludes a two-dimensional semiconductor material over and contacting atop surface and sidewalls of the first gate dielectric layer. The devicealso includes a source region over and contacting a first end of thetwo-dimensional semiconductor material, and further contacting the firstgate dielectric layer. The device also includes a drain region over andcontacting a second end of the two-dimensional semiconductor material,and further contacting the first gate dielectric layer, the second endbeing an opposite end from the first end. The device also includes asecond gate dielectric layer over and contacting top surfaces of thetwo-dimensional semiconductor material, the source region, and the drainregion. The device also includes a second gate electrode over the secondgate dielectric layer. The device also includes and source/draincontacts extending through the second gate dielectric layer andcontacting the source region and the drain region.

Embodiments may include one or more of the following features. Thedevice further including a third gate electrode over the dielectriclayer, the first gate dielectric layer over and contacting a top surfaceand sidewalls of the third gate electrode, the third gate electrodebeing spaced apart from the first gate electrode.

The foregoing outlines features of several embodiments so that thoseskilled in the art may better understand the aspects of the presentdisclosure. Those skilled in the art should appreciate that they mayreadily use the present disclosure as a basis for designing or modifyingother processes and structures for carrying out the same purposes and/orachieving the same advantages of the embodiments introduced herein.Those skilled in the art should also realize that such equivalentconstructions do not depart from the spirit and scope of the presentdisclosure, and that they may make various changes, substitutions, andalterations herein without departing from the spirit and scope of thepresent disclosure.

What is claimed is:
 1. A method comprising: forming a first gateelectrode over a substrate; forming a first gate dielectric layer overthe first gate electrode; depositing a semiconductor layer over thefirst gate dielectric layer; forming source/drain regions over the firstgate dielectric layer and the semiconductor layer, the source/drainregions overlapping ends of the semiconductor layer; forming a secondgate dielectric layer over the semiconductor layer and the source/drainregions; and forming a second gate electrode over the second gatedielectric layer.
 2. The method of claim 1, wherein the depositing thesemiconductor layer comprises depositing a transition metaldichalcogenide layer.
 3. The method of claim 2, wherein the transitionmetal dichalcogenide layer comprises comprise MoS₂, MoSe₂, WS₂, WSe₂, orInSe.
 4. The method of claim 2, wherein the transition metaldichalcogenide layer is performed using chemical vapor deposition withMoO₃ powder and sulfur powder as precursors.
 5. The method of claim 1,wherein the depositing the semiconductor layer comprises depositing asemiconductor oxide layer.
 6. The method of claim 5, wherein thesemiconductor oxide layer comprises zinc oxide or indium gallium zincoxide.
 7. The method of claim 1, wherein the first gate dielectric layerand the second gate dielectric layer each comprise a high-k dielectricmaterial.
 8. The method of claim 1 further comprising: forming anisolation layer over the substrate, the first gate electrode being overthe isolation layer.
 9. The method of claim 1 further comprising:forming a third gate electrode over the substrate, the first gatedielectric layer and the semiconductor layer being over the third gateelectrode, the third gate electrode being spaced apart from the firstgate electrode.
 10. The method of claim 1, wherein the semiconductorlayer is a conformal layer.
 11. A device comprising: a first gateelectrode over a substrate; a first high-k gate dielectric layer overthe first gate electrode; a transition metal dichalcogenide layer overthe first high-k gate dielectric layer; source/drain regions over thefirst high-k gate dielectric layer and the transition metaldichalcogenide layer, the source/drain regions overlapping ends of thetransition metal dichalcogenide layer; a second high-k gate dielectriclayer over the transition metal dichalcogenide layer and thesource/drain regions; and a second gate electrode over the second high-kgate dielectric layer.
 12. The device of claim 11, wherein thetransition metal dichalcogenide layer comprises a plurality ofmonolayers.
 13. The device of claim 11, wherein the transition metaldichalcogenide layer comprises comprise MoS₂, MoSe₂, WS₂, WSe₂, or InSe.14. The device of claim 11 further comprising: a third gate electrodeover the substrate, the first high-k gate dielectric layer and thetransition metal dichalcogenide layer being over the third gateelectrode, the third gate electrode being spaced apart from the firstgate electrode.
 15. The device of claim 14, wherein the transition metaldichalcogenide layer has a bottom surface lower than top surfaces of thefirst gate electrode and the third gate electrode.
 16. The device ofclaim 11, wherein the device is configured to operate as a NAND gatewith the first gate electrode and the second gate electrode being inputsto the NAND gate and one of the source/drain regions being an output ofthe NAND gate.
 17. The device of claim 11, wherein the device isconfigured to operate as a NOR gate with the first gate electrode andthe second gate electrode being inputs to the NOR gate and one of thesource/drain regions being an output of the NOR gate.
 18. A devicecomprising: a dielectric layer; a first gate electrode over thedielectric layer; a first gate dielectric layer over and contacting atop surface and sidewalls of the first gate electrode; a two-dimensionalsemiconductor material over and contacting a top surface and sidewallsof the first gate dielectric layer; a source region over and contactinga first end of the two-dimensional semiconductor material, and furthercontacting the first gate dielectric layer; a drain region over andcontacting a second end of the two-dimensional semiconductor material,and further contacting the first gate dielectric layer, the second endbeing an opposite end from the first end; a second gate dielectric layerover and contacting top surfaces of the two-dimensional semiconductormaterial, the source region, and the drain region; a second gateelectrode over the second gate dielectric layer; and source/draincontacts extending through the second gate dielectric layer andcontacting the source region and the drain region.
 19. The device ofclaim 18 further comprising: a third gate electrode over the dielectriclayer, the first gate dielectric layer over and contacting a top surfaceand sidewalls of the third gate electrode, the third gate electrodebeing spaced apart from the first gate electrode.
 20. The device ofclaim 15, wherein the two-dimensional semiconductor material comprises atransition metal dichalcogenide layer.